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    废弃风电叶片长度对回收产物及玻璃纤维的影响

    Effect of waste wind turbine blade length on recycled products and glass fiber

    • 摘要: 近20 a来,随着风电技术的发展,每年有近5万t风电叶片达到退役年限,且这一数值逐年增加。废弃风电叶片作为一种回收难度较高的复合材料,如何合理有效地进行资源再利用成为亟须解决的问题。在诸多方法中,热解因适用范围广、回收效率高等优势,被认为是回收废弃风电叶片最有前途的技术之一。然而很少有人关注废弃风电叶片原料长度对热解产物及回收纤维的影响。为探究废弃风电叶片长度对热解过程及回收纤维强度的影响,在管式炉中对不同长度的废弃风电叶片进行了等温热解实验,热解后的产物经过马弗炉氧化后得到纯净纤维。实验结果表明:三相产物中固体产率最高,约为68.28%~85.86%;气体产率最低,约为1%。热解气主要由CO2、CO和C1–C3等烷烃组成,其中,CH4体积分数达到39.66%,热解气的热值约26.16~34.11 MJ/Nm3。热解油主要由酚类化合物组成,含有大量高价值化工原料如双酚A、苯酚等,且碳原子数位于6~19的化合物质量分数达到63%以上。此外,风电叶片长度的增加可以有效提高回收纤维的拉伸强度,当废弃风电叶片长度从5 cm增加到25 cm时,纤维的强度从383.9 MPa提高到659.73 MPa。

       

      Abstract: In the past 20 years, with the development of wind power technology, nearly 50000 tons of wind turbine blades have reached retirement age every year, and this number has increased year by year. As a composite material with high difficulty in recycling, waste wind turbine blades have become an urgent problem to be solved in terms of how to reasonably and effectively reuse resources. Among many methods, pyrolysis is considered to be one of the most promising technologies for recycling waste wind turbine blades due to its wide range of applications and high recycling efficiency. However, few people pay attention to the effect of the length of waste wind turbine blade raw materials on pyrolysis products and recycled fibers. In order to explore this influencing factor, isothermal pyrolysis experiments were carried out on waste wind turbine blades of different lengths in a tubular furnace. The pyrolysis products were oxidized in a muffle furnace to obtain pure fibers. The experimental results show that the solid yield is the highest among the three-phase products, about 68.28%–85.86%; and the gas yield is the lowest, about 1%. Pyrolysis gas is mainly composed of CO2, CO and C1–C3 alkanes, among which the CH4 content reaches 39.66%, and the calorific value of pyrolysis gas is about 26.16–34.11 MJ/Nm3. Pyrolysis oil is mainly composed of phenolic compounds, containing a large amount of high-value chemical raw materials such as bisphenol A, phenol, etc., and the content of compounds with carbon atoms between 6–19 reaches more than 63%. In addition, the increase in the length of the wind turbine blade can effectively improve the tensile strength of the recycled fiber. When the length of the waste wind turbine blade increases from 5 cm to 25 cm, the strength of the fiber increases from 383.9 MPa to 659.73 MPa.

       

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