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    富氧燃烧烟气净化工艺研究进展

    Research and development on the purification technology for oxy-fuel combustion flue gas

    • 摘要: 随着工业的快速发展,化石燃料的消耗与日俱增,造成了大量温室气体CO2 的排放,全球气候变化形势不容乐观。为了减少CO2 的排放,需要对高浓度的CO2 进行捕获、利用与封存,而富氧燃烧技术能有效地实现碳捕集,是目前最具有潜力的碳减排技术之一。富氧燃烧过程中,SOx、NOx、Hg 等污染物以及惰性气体的存在不利于碳的捕集与封存。由于烟气中的各成分浓度会对管道运输、地质储存和提高采收率(EOR)产生影响,文中首先介绍了烟气中CO2 及各种杂质浓度的不同标准,然后系统综述了国内外脱硫、脱硝、脱汞和惰性气体脱除以及联合脱除技术的研究进展。SOx 脱除技术分为干法脱硫技术、湿法脱硫技术以及半干法脱硫技术,其中石灰石/石膏湿法脱硫技术是目前应用最广泛也最成熟的烟气脱硫技术,并描述了富氧燃烧烟气中CO2 气氛对SOx 脱除的影响。NOx 脱除技术除了传统的选择性催化还原技术(SCR)、选择性非催化还原技术(SNCR)外,重点描述了氧化吸收法脱硝技术以及加压条件下NO 的氧化机理。总结了Hg 脱除技术中不同烟气成分对Hg 氧化的影响,论述了活性炭以及活性炭改性后对Hg 脱除的影响。介绍了惰性气体的净化技术,主要采用变压吸附方法来吸附和解吸附,降低了CO2 气流中惰性气体去除的成本。重点讨论了在烟气压缩液化系统中的联合脱除技术,有效地利用压缩过程条件将SOx、NOx、Hg 分别以硫酸、硝酸、Hg(NO3)2 形式协同去除,提出了高压下NO2 与Hg 反应产物的不确定性,简单介绍了低温碳捕集技术的研究进展。最后对未来研究方向进行展望。

       

      Abstract: With the rapid development of industry,the consumption of fossil fuels is increasing with each passing day,resulting in a large amount of greenhouse gas CO_2 emissions.The situation for global climate change is not optimistic.In order to reduce the emission of CO_2,it is necessary to capture,utilize and store the high concentration of CO_2.Oxy-fuel combustion technology can effectively achieve carbon capture,which is considered as one of the most potential carbon emission reduction technologies.In the process of oxy-fuel combustion,the existence of pollutants(including SO_x,NO_xand Hg) and inert gas is not conducive to carbon capture and storage.Since the concentration of various components in flue gas will affect pipeline transportation,geological storage,and enhanced oil recovery(EOR),the different standards of CO_2 and various impurities concentration in flue gas were introduced firstly,and the research progress of desulfurization,denitrification,mercury removal,inert gas removal,and combined removal technologies at home and abroad was systematically reviewed.In addition to the introduction of traditional desulfurization technology,the influence of CO_2 atmosphere in oxy-fuel combustion flue gas on SO_x removal and the conversion and removal of SO_2 under pressure were mainly described.It is found that the absorption rate of SO_2 in CO_2 atmosphere is lower than that in N_2 atmosphere,and the critical pH changes during the absorption process.In the denitration section,the denitration technology by oxidation absorption method and the oxidation mechanism of NO under high pressure were mainly described,and the oxidation kinetics of NO under high pressure was described.With the increase of pressure,the NO oxidation rate constant first decreases and then increases,which is proved that the effect of reactor pressure on liquid entrainment rate is significant.The effects of different flue gas components on Hg oxidation in Hg removal technology were summarized.HCl and Cl_2 play a significant role in promoting Hg oxidation.The activated carbon is modified to increase the specific surface area of pore structure and the active sites on the surface of adsorbent,so as to improve the removal efficiency of Hg.In this paper,the purification technology of inert gas was introduced.Pressure swing adsorption method is mainly used to adsorb and desorb,which reduces the cost of inert gas removal in CO_2 gas flow,realizes a part of inert gas recycling back to the boiler,and improves CO_2 capture.The combined removal technology in the flue gas compression liquefaction system is mainly discussed,which effectively uses the compression process conditions to remove SO_x,NO_x and Hg in the form of sulfuric acid,nitric acid and Hg(NO_3)_2.With the increase of pressure,the removal efficiency of SO_x and NO_x increases,which is conducive to the formation of SO_4~(2-),NO_3~-,HADS and HAMS(N-S compounds),and also leads to the increase of N_2O production.It is proved that the reaction of Hg with NO_2 is a gas phase reaction,and the uncertainty of the product of the reaction of NO_2 with Hg under high pressure is proposed.The low temperature carbon capture technology is briefly introduced,which has the potential to replace the scrubber and other flue gas treatment methods,but there is still a lack of feasibility research.In the future,it is necessary to explain the change trend of NO oxidation rate constant under different pressures,analyze the products of NO_x and SO_x combined removal and the reaction products of NO_2 and Hg under high pressure.

       

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