SCR脱硝反应区域运行温度影响因素研究
Influencing factors of operating temperature of denitration SCR reactor
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摘要: 针对降低SCR脱硝反应区域运行温度后造成催化剂失活的问题,以600 MW燃煤机组典型SCR脱硝反应系统为研究对象,分析了脱硝SCR催化反应温度、催化剂区域硫酸氢铵生成温度、还原剂稀释风、测温元件允许误差等对机组脱硝反应区域温度的影响,确定SCR反应器区域最低运行温度安全值。结果表明,钒钨钛系催化剂的活性温度窗口为320~420℃,最佳反应温度窗口主要集中在340~380℃,SCR脱硝反应效率达到最高约90%;SCR反应器入口的气相主体硫酸氢铵的凝结温度为270~320℃;喷氨稀释风会降低SCR反应器运行温度,温度降低2.6~2.9℃;温度测量元件的允许误差对SCR反应器系统测量温度造成相对固定的影响,造成温度最大偏低约4℃。提出SCR脱硝反应器进口温度应集中在350~390℃。Abstract: The lower operating temperature of SCR denitration reactor directly caused catalyst deactivation. In order to resolve this problem,taking the typical SCR denitration system of 600 MW coal- fired unit as research object,the influence of reaction temperature,NH3HSO4 formation temperature in catalytic reaction region,sprayed ammonia diluted wind and permissible error of temperature measurement components on the temperature of denitration area was analyzed. The minimum safe operating temperature of SCR denitration reactor was determined. The results showed that,the activation temperature of vanadium- tungsten- titanium catalyst ranged from 320 ℃ to 420 ℃. When the temperature was between 340 ℃ and 380 ℃,the reaction had the best performance and the denitration efficiency reached about 90%.The condensation temperature of NH3HSO4 which was the major component in gas phase was between 270 ℃ and 320 ℃. The sprayed ammonia diluted wind reduced the denitration temperature by 2. 6 ℃ to 2. 9 ℃. The permissible error of temperature measurement components had relatively fixed influence on SCR denitration reactor,the maximum reduction was about 4 ℃. At last,the inlet temperature was determined in the range of 350 ℃ and 390 ℃.
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