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    金属氢化物储氢/放氢过程中热管理技术的研究现状及进展

    Research status and progress of thermal management technology in metal hydride hydrogen absorption and desorption processes

    • 摘要: 金属氢化物储氢因其高安全性和较高储氢密度,在未来氢能产业中展现出广阔的应用前景。然而,储氢/放氢过程伴随剧烈的放热/吸热反应,且储氢合金在循环过程中易发生反复胀缩,导致床层热导率降低,引起储氢/放氢性能衰减。因此,热管理技术成为提升储氢/放氢性能的关键。研究梳理了近年来在金属氢化物储氢反应器的几何形状、储氢材料改性、外部冷却系统以及内部换热结构(翅片、圆管和螺旋管等)等方面的研究进展。结果表明:不同几何形状的反应器在传热效率和空间利用率方面各有特点,通过掺杂高热导率介质与优化换热结构可显著改善温度场分布并缩短储氢/放氢时间,但会降低储氢容量;外部冷却系统虽能增强整体传热能力,但内部冷却结构在缓解局部过热方面更具优势;复杂的翅片结构与螺旋管结构在提升换热效率和减小温度梯度方面表现优异。虽然制造成本与结构复杂性仍是应用瓶颈,但热管理技术的持续创新已为金属氢化物储氢反应器在规模化应用与工程化推广中提供了坚实基础。

       

      Abstract: Metal hydride hydrogen storage is regarded as having broad application potential in the future hydrogen energy industry due to its safety and high hydrogen storage density. However, the hydrogen absorption and desorption processes are accompanied by intense exothermic/endothermic reactions. During cycling, hydrogen storage alloys are prone to repeated expansion and contraction, resulting in a decrease in thermal conductivity and a decline of hydrogen absorption and desorption performance. Therefore, thermal management technology is recognized as the critical element for enhancing hydrogen absorption and desorption performance. Research progress in metal hydride hydrogen storage reactors over recent years is summarized, with a focus on reactor geometry, modification of hydrogen storage materials, external cooling systems, and internal heat exchange structures including fins, circular tubes and helical tubes. Results show that reactors with different geometries exhibit distinct characteristics in heat transfer efficiency and space utilization. Doping high thermal conductivity media and optimizing the heat exchange structures are found to significantly improve temperature uniformity and to shorten hydrogen absorption and desorption time, while hydrogen storage capacity is reduced. Although external cooling systems can enhance the overall heat transfer capacity of the hydrogen storage reactor, internal cooling structures are regarded as more effective in alleviating local overheating. Complex fin structures and helical tube structures are demonstrated to excel in improving heat exchange efficiency and reducing temperature gradients. Although manufacturing cost and structural complexity remain application barriers, a solid foundation for the scaled application and engineering deployment of metal hydride hydrogen storage reactors is established by continuous innovation in thermal management technologies.

       

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