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    全固态锂电池热失控研究进展及展望

    Research progress and prospects on thermal runaway of all solid-state lithium battery

    • 摘要: 全固态锂电池(All Solid-State Lithium Battery, ASSLB)的热失控问题因高能量密度下剧烈的放热特征,已成为制约其技术发展的核心瓶颈之一。围绕ASSLB热失控特性,从材料、界面及电池整体多层面总结了相关研究进展,系统解析了热失控各层面的内在关联。首先,分析ASSLB热失控的潜在放热反应及其由触发到失控的阶段性演化过程;其次,从材料层面总结主要固态电解质(聚合物、氧化物和硫化物)的综合性能、热分解温度及特性研究现状;然后,解析固态电解质与正负电极界面热失控的诱发原因,介绍主流电极材料与固态电解质热失控特性研究进展;最后,概述电池层面的热失控研究进展,梳理当前ASSLB热失控防控策略。结果表明:聚合物固态电解质具备良好的可加工性但热稳定性有限,氧化物固态电解质热稳定性优而界面阻抗大,硫化物固态电解质虽离子电导率高但热稳定性差且易产毒气;正极晶格氧释放与界面反应耦合是导致温升剧烈的核心环节。基于此,提出需构建从材料热稳定性到电芯/模组热安全的跨尺度评估框架,并重点发展融合原位传感与智能算法的主动早期预警策略,以推动ASSLB热安全从被动防护向主动管控的范式转变。

       

      Abstract: Thermal runaway in the all-solid-state lithium battery (ASSLB) represents a primary bottleneck for technological evolution because of the violent exothermic characteristics associated with high energy density. A multi-level summary of research progress on the thermal runaway characteristics of ASSLB across the material, interface, and overall cell levels is provided, alongside a systematic analysis of the intrinsic correlations among these hierarchies. First, the potential exothermic reactions of ASSLB thermal runaway and its staged evolution from triggering to runaway are analyzed. Second, from the material level, the comprehensive performance, thermal decomposition temperatures, and research status of major solid-state electrolyte (polymer, oxide, and sulfide) are summarized. Then, the causes of thermal runaway at the interface between solid-state electrolyte and positive/negative electrodes are elucidated, and the research progress on the thermal runaway characteristics of mainstream electrode materials and solid-state electrolyte is introduced. Finally, the research progress of thermal runaway at the battery level is outlined, and the current prevention and control strategies for ASSLB thermal runaway are reviewed. The result indicates that polymer solid-state electrolyte possess good processability but limited thermal stability; oxide solid-state electrolyte exhibits excellent thermal stability but high interfacial impedance; sulfide solid-state electrolyte, despite high ionic conductivity, suffers from poor thermal stability and a tendency to generate toxic gases. The coupling between lattice oxygen release from the cathode and interfacial reactions is the core mechanism leading to the drastic temperature rise. Based on this, it is proposed that a cross-scale evaluation framework from material thermal stability to cell/module thermal safety should be constructed, and that proactive early warning strategies integrating in-situ sensing and intelligent algorithms should be developed, so as to promote a paradigm shift in ASSLB thermal safety from passive protection to active management.

       

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