高级检索

    氢液化与低温高压储氢技术发展现状

    Review on hydrogen liquefaction and cryo-compression hydrogen storage technologies

    • 摘要: H2来源广泛、清洁无碳,是未来重要的清洁二次能源载体,在世界能源格局中占重要地位。H2低温致密化技术可大幅提高储氢密度,有效解决H2低密度、低沸点带来的大规模储运难题。综述了氢液化与低温高压储氢2种低温储氢技术的发展现状,对比了各类低温储氢流程的性能和特点,总结了未来发展方向,为H2储运技术的发展提供参考。其中低温液态储氢(氢液化)的储氢密度高且储氢压力低,是目前主流的大规模氢储运方法之一;低温高压储氢则可达到与液氢接近的储氢密度,且本征能耗低、无需正仲氢转化,极具发展潜力;而采用以混合工质节流制冷循环为代表的闭式低温制冷循环替代液氮对H2进行预冷或冷却,可显著降低H2低温致密化能耗,是2种低温储氢技术的重要发展趋势。

       

      Abstract: Hydrogen is an important clean and carbon-free secondary energy carrier in the future due to its extensive source, clean and carbon free, which will play a significant role in the world energy pattern. Hydrogen cryogenic densification technology can greatly improve hydrogen storage density and effectively solve the problems in large-scale storage and transportation caused by the low density and low boiling point of hydrogen. The developments of two cryogenic hydrogen storage technologies, hydrogen liquefaction and cryo-compressed hydrogen, were reviewed in this paper. The performance and characteristics of various cryogenic densification processes were introduced and compared, and the future development directions were summarized, providing a reference for the development of hydrogen storage and transportation technologies. Hydrogen liquefaction can achieve high hydrogen storage density with low hydrogen storage pressure, which is one of the mainstream large-scale hydrogen storage and transportation method at present. Cryo-compressed hydrogen could also reach a high storage density near liquid hydrogen with advantages of low intrinsic energy consumption and free of ortho-to-para hydrogen conversion, which has great development potential. Besides, closed refrigeration cycles such as mixed-refrigerant J-T cycles can effectively replace liquid nitrogen in the precooling or cooling hydrogen, which can significantly reduce the energy consumption of hydrogen densification and is an important development trend of cryogenic hydrogen storage technologies.

       

    /

    返回文章
    返回