高级检索

    低流量低分压CO2条件下有机胺多轮次循环吸收性能研究

    Study on multi-cycle absorption properties of organic amines at low flow rate and low partial pressure CO2

    • 摘要: 为了评估有机胺吸收剂对于低流量、低浓度、低分压CO2的吸收–解吸循环的稳定性,采用表观循环容量占最大循环容量百分比、20次循环容量作为有机胺吸收剂循环吸收稳定性的2个性能参数,研究了乙醇胺(MEA)、三乙烯四胺(TETA)、N–甲基二乙醇胺(MDEA)以及MDEA+TETA这4种吸收剂的吸收、解吸性能、表观循环容量占最大循环容量百分比以及20次吸收–解吸循环的循环容量。结果表明,采用的2个性能参数能够直观反映吸收剂在有限条件下捕集CO2的容量与能够达到的最大容量的差距以及在吸收−解吸循环过程中的性能变化。MDEA与TETA混合吸收剂的表观循环容量占最大循环容量百分比较高,达到78.10 %,且能够在多次吸收–解吸过程中保持更高的循环容量,20次循环中循环容量最大达到0.75 mol CO2/mol amine且稳定性较强,对捕集工业化石燃料燃烧后排放烟气中的CO2有较好的潜力。

       

      Abstract: To evaluate the stability of an amine absorbent for the absorption-desorption cycle of low-flow, low-concentration, low-partial-pressure CO2, the ratio of apparent cycle capacity to maximum cycle capacity and the capacity of 20 cycles were used as two performance parameters for the absorption stability of organic amine absorbent, the absorption and desorption properties, the ratio of apparent cycle capacity to the maximum cycle capacity and the cycle capacity of 20 absorption-desorption cycles of Ethanolamine (MEA), Triethylenetetramine (TETA), N–Methyldiethanolamine (MDEA) and MDEA + TETA were studied. The result shows that the ratio of apparent cycle capacity to maximum cycle capacity can directly reflect the differences between the CO2 absorption properties in limited conditions and the maximum absorption properties. The capacity of 20 cycles reflects the changes of amine absorbents’ ability to transport CO2 during the absorption-desorption cycle. The ratio of the apparent cycle capacity to the maximum cycle capacity of MDEA/TETA mixed absorbent is the highest, reaching 78.10%, and it can keep a higher cycle capacity in the multi-absorption-desorption process. The maximum capacity of MDEA/TETA mixed absorbent in the 20 cycles is 0.75 mol CO2/mol amine, which is relatively stable thus has a good potential for capturing CO2 in flue gas from industrial fossil fuel combustion.

       

    /

    返回文章
    返回