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    300 MW CFB锅炉SNCR+SCR深度脱硝性能研究

    Study on deep denitrification performance of SNCR+SCR for a 300 MW CFB boiler

    • 摘要: 随着环保压力不断提高,流化床锅炉需进行深度脱硝改造以实现超低排放,但目前SCR改造在流化床锅炉上的应用研究较少。某厂320MW流化床机组改造增加了SCR脱硝系统,基于该工程改造项目,笔者使用网格法对烟气场温度、烟气成分等参数进行测定,进行了改造前后的锅炉性能试验,研究了改造后SCR的脱硝性能及其影响因素,并测试锅炉效率。结果表明,不同负荷下,SCR入平均温度在268.11~309.53℃,基本满足拓展的SCR反应温度窗(260~420℃)。机组满负荷320MW下,实测反应器脱硝效率为72.48%,对应的氨逃逸浓度为0.7mg/Nm3。40%~100%负荷下,NOx排放均低于25mg/Nm3,氨逃逸浓度不大于1mg/Nm3。由于烟气温度水平较煤粉炉低,因此本试验中SCR反应器的脱硝效率低于应用于煤粉炉的SCR反应器。40%~100%负荷下的尿素耗量均低于同等级的煤粉锅炉,其中满负荷下的尿素耗量为279.09kg/h。在相同排放数值下尿素耗量降低50%以上,节能降耗效果显著。排放结果与尿素耗量统计结果表明,SNCR与SCR耦合良好,应用于CFB锅炉具有较大优势。SCR出处NOx分布并不均匀,在烟道水平截面上呈NOx浓度右侧高、左侧低的趋势,与SCR入温度分布一致,温度是影响脱硝效率和NOx分布的主要因素。改造后平均锅炉效率为90.07%,与改造前锅炉效率持平,表明SCR改造对锅炉效率影响较小。锅炉90%以上热损失由排烟和物理未完全燃烧热损失造成,控制排烟热损失q2和物理未完全燃烧热损失q4是锅炉热效率提升的关键。

       

      Abstract: With the continuous improvement of environmental protection pressure,in-depth denitrification retrofit for many fluidized circulating bed( CFB) boilers needs to be carried out to achieve ultra-low emissions,while there is little research on the application of SCR retrofit in CFB boilers at present. SCR denitrification system has been added to a 320 MW fluidized bed unit. Based on this project,the grid method was used to measure the parameters of flue gas temperature,flue gas composition,etc.,the boiler performance test before and after the retrofit was carried out,and the denitrification performance and its influencing factors after SCR retrofit were studied. Besides,the boiler efficiency was measured. The results show that the average temperature at SCR inlet is 268.11-309.53 ℃ under different loads,which basically meets the extended temperature window for SCR reaction( 260-420 ℃) . With 320 MW load,the measured denitrification efficiency is 72.48%,and the corresponding ammonia escape concentration is 0.7 mg/Nm3. Under 40%-100% load,the NOxemission is lower than 25 mg/Nm3,and the ammonia escape concentration is lower than 1 mg/Nm3. Because the flue gas temperature is lower than that of pulverized coal boiler,the denitrification efficiency of SCR reactor in this test is lower than that used in pulverized coal boiler. The urea consumption under 40%-100% load is lower than that of pulverized boiler with the same grade,and the urea consumption under full load is 279.09 kg/h. Under the same emission value,the urea consumption is reduced by more than 50%,and the effect of energy saving is significant. The results of emission and urea consumption show that SNCR are well coupled with SCR,and this technology has a great advantage in CFB boiler. The NOxdistribution at the SCR outlet is not uniform,showing a trend of high NOxconcentration on the right side and low NOxconcentration on the left side on the horizontal section of flue,which is consistent with the temperature distribution at the SCR inlet. Temperature is the main factor affecting the denitrification efficiency and NOxdistribution. The average boiler efficiency after retrofit is 90.07%,which is basically equal to that before retrofit,indicating that SCR retrofit has little effect on boiler efficiency. More than 90%of the heat loss of the boiler is caused by the heat loss of exhaust gas and incomplete combustion. The key to improve the boiler thermal efficiency is to reduce q2( heat loss of exhaust gas) and q4( incomplete combustion of solid).

       

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