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    脱硫湿烟气喷淋冷凝过程数值模拟研究

    Numerical simulation of spray condensation process of desulfurized wet flue gas

    • 摘要: 大中型燃煤电厂多采用湿法脱硫技术,脱硫过程导致大量水分蒸发,600MW机组经湿法脱硫后排放的烟气中携带水蒸气超过200t/h。脱硫湿烟气中的水蒸气及低温余热是燃煤电厂水资源和能量损耗的重要部分。为降低烟气中的含湿量,有效回收烟气中的水分及余热,同时解决因湿烟气中水蒸气凝结引起的烟囱腐蚀、“石膏雨”及“白烟”等问题,基于Fluent软件,构建三维稳态CFD模型,对湿法脱硫后烟气的冷凝过程进行数值模拟研究,将优化设计后的冷凝室作为计算对象,充分考虑气液两相流之间的能量、质量、动量交换,全面讨论了冷凝室本身结构和气液两相参数对传热传质的影响。结果表明:两喷淋层的布置存在最佳间距,模拟中最佳间距为1m,此间距可使液滴在冷凝室内停留时间和气液接触均匀性同时达到较高水平。在一定的烟气流速范围内,烟气流速高,烟气在冷凝室中停留时间短,气液两相接触时间少,换热程度差;烟气流速低,烟气雷诺数小,湍流流动弱,单位时间单位面积处理的空气量小,故存在最佳烟气流速,研究表明,最佳烟气流速为3.5m/s。适当增大液气比、合理减小液滴直径、降低喷淋液温度、加大喷嘴角度,都可有效保证流场均匀性,提高气液接触强度,增强气液之间传热传质效果。但增大液气比需较大水量,不利于节水节能;降低喷淋液温度可加大换热温差,但需较低的冷却水源;加大喷嘴角度对提高冷凝效果幅度有限。其中减小液滴直径是最有效的方法,采用雾化程度好的喷嘴,使液滴直径小于210μm,可将湿烟气从323K冷凝至311.75K,600MW机组每小时可回收至少80t水资源以及6.59MW能量,达到节水节能、“消白”、除尘一体化的目的。

       

      Abstract: Wet desulfurization technology is mostly adopted in large and medium-sized coal-fired power plants,which results in a large amount of water evaporation in the desulfurization process. For 600 MW units,the flue gas discharged after wet desulfurization carries more than 200 t/h of water vapor. Water vapor and low-temperature waste heat in desulfurization wet flue gas are important parts of water resources and energy loss in coal-fired power plants. In order to reduce the moisture content in flue gas,effectively recover the moisture and waste heat in flue gas,and solve the problems such as chimney corrosion, " gypsum rain" and " white smoke" caused by condensation of water vapor in wet flue gas,a three-dimensional steady-state CFD model was built based on fluent software to simulate the condensation process of flue gas after wet desulfurization. Taking the optimized condensation chamber as the calculation object,the energy,mass and momentum exchange between gas-liquid two-phase flows were fully considered. The influence of the structure of the condensation chamber itself and the gas-liquid two-phase parameters on heat and mass transfer was comprehensively discussed. The results show that there is an optimal spacing between the two spray layers,and the optimal spacing in the simulation is 1 m. This spacing can make the residence time of liquid droplets in the condensation chamber and the gas-liquid contact uniformity reach a higher level at the same time. Within a certain range of flue gas velocity,the flue gas velocity is high,the residence time of flue gas in the condensation chamber is short,the contact time between gas and liquid is short,and the degree of heat exchange is poor. The flue gas flow rate is low,the flue gas Reynolds number is small,the turbulent flow is weak,and the amount of air treated per unit area per unit time is small,therefore,there is an optimal flue gas flow rate. The research shows that the optimal flue gas flow rate is 3.5 m/s. Proper increase of liquid-gas ratio,reasonable reduction of droplet diameter,reduction of spray liquid temperature and increase of nozzle angle can effectively ensure the uniformity of flow field,improve the gas-liquid contact strength and enhance the heat and mass transfer effect between gas and liquid. However,increasing the liquid-gas ratio requires a larger amount of water,which is not conducive to saving water and energy. Reducing the temperature of spray liquid can increase the temperature difference of heat exchange,but a lower cooling water source is required. Increasing the nozzle angle has limited effect on improving condensation. Among them,the most effective method is to reduce the droplet diameter. Using a nozzle with good atomization degree,the droplet diameter is less than 210 μm,which can condense wet flue gas from 323 K to 311. 75 K. For600 MW units,at least 80 t of water resources and 6.59 MW of energy can be recovered per hour,so as to achieve the goal of water saving and energy saving, " white elimination" and dust removal integration.

       

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