高级检索

    流化数对加压流化床煤催化加氢气化过程影响的数值模拟

    Numerical simulation on the effect of fluidization number in pressurized fluidized bed coal catalytic hydrogasification

    • 摘要: 加压流化床煤催化加氢气化技术因其高碳转化率和甲烷产率,在煤制天然气领域展现出广阔的应用前景。流化数作为影响流化床气化炉性能的关键参数,通过调控床层内颗粒运动混合及气固传质传热过程,对气化炉温度分布、碳转化率、甲烷产率具有重要影响。然而,目前关于流化数的系统性研究较为匮乏,深入揭示其对气化“三传一反”过程的作用机制对工艺参数优化和反应器设计具有重要意义。基于计算流体力学模拟,采用多相质点网格模型(MP-PIC),系统研究了2.0、3.5、5.0、8.0四种流化数对催化加氢气化的影响规律。研究发现,较低流化数条件下生成的气泡尺寸较小,可有效提升碳−氢传质效率,强化气化反应过程,提高床层热点温度。2.0倍流化数工况的热点峰值温度可达1555 K,超过了煤灰的熔融温度。流化数的增加促进了颗粒在床内的运动扩散,导致热点温度分散下降,其余流化数工况下的最高温度均在1300 K以下。在综合考虑反应强化与热点控制的基础上,3.5倍的流化数是较佳选择。此外,还追踪了不同粒径的代表性颗粒,通过分析它们的运动轨迹、温度演变及反应性,发现初始直径为196 μm的颗粒在高温区与小气泡强化传质区域的协同作用下,展现出最佳的加氢反应特性。过大或者过小的颗粒会因堆积在床层底部或者被夹带至稀相区而影响其反应性。相应结果可以为流化床煤气化炉的设计和优化提供理论指导。

       

      Abstract: Pressurized fluidized bed coal catalytic hydrogasification technology demonstrates broad application prospects in the coal-to-natural gas field due to its high carbon conversion rate and methane yield. The fluidization number, as a key parameter affecting the performance of fluidized bed gasification, plays a significant role in regulating particle motion, mixing, and gas-solid mass and heat transfer processes within the bed, thereby influencing the temperature distribution, carbon conversion rate, and methane yield in the gasifier. However, systematic research on the fluidization number remains scarce, and a deeper understanding of its mechanism in the flow-transfer-reaction process of gasification is crucial for optimizing process parameters and reactor design. This study, based on computational fluid dynamics (CFD) simulation and employing the multiphase particle-in-cell (MP-PIC) model, investigates the effects of four fluidization numbers (2.0, 3.5, 5.0 and 8.0) on the coal catalytic hydrogasification performance. The results reveal that smaller bubble sizes generated under lower fluidization numbers effectively enhance carbon-hydrogen mass transfer efficiency, intensify the hydrogasification reaction process, and elevate the hot spot temperature in the bed. The peak hot spot temperature under the 2.0 fluidization number condition reaches 1555 K, exceeding the melting temperature of coal ash. An increase in the fluidization number promotes particle diffusion and movement within the bed, leading to a more dispersed and reduced hot spot temperature, with the maximum temperatures under the other three fluidization number conditions below 1300 K. Considering both reaction intensification and hot spot control, a fluidization number of 3.5 is identified as a recommended choice. Furthermore, this study tracks representative particles of different sizes, analyzing their motion trajectories, temperature evolution, and reactivity. It is found that particles with an initial diameter of 196 μm exhibit the best hydrogasification reaction characteristics under the synergistic effects of the high-temperature zone and the small-bubble-enhanced mass transfer region. Particles that are either too large or too small tend to accumulate at the bottom of the bed or become entrained into the dilute phase region, negatively impacting their reactivity. The corresponding results can provide theoretical guidance for the design and optimization of fluidized bed coal gasifiers.

       

    /

    返回文章
    返回