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    污泥热解反应程度对产物组分及分布的影响

    Influence of sludge pyrolysis reaction degree on product composition and distribution

    • 摘要: 针对我国市政污泥资源化、减量化处置的发展需求,可利用热解技术将其转化为焦油、可燃气和半焦等产品。通过改变反应温度及时间进而调变污泥热解反应程度,考察了不同反应程度对污泥热解转化规律及其热解产物分布特性的影响。结果表明,不同热解反应时间对三相产物产率及组成的影响显著,且随温度变化也有一定的差异。随着反应时间延长,半焦产率逐渐降低,热解气产率大幅增加。当热解温度500 ℃时,与反应时间为0 min相比,30 min时CO2、C2-C3产率分别增加了171.9%、1287.2%;而高温700 ℃时,热解气中各组分产率的增长率下降。碳酸盐分解形成的CO2可与污泥焦发生气化反应,进而形成CO。污泥焦油以重质组分为主,如沸点>230 ℃的馏分油共占90%以上。反应时间增加后,焦油中轻质组分(<230 ℃)产率提高了131.5%(500 ℃);而700 ℃ 时焦油各馏分产率变化幅度较低,这是因为热解反应温度较高,污泥结构受热充分,热分解反应进行更为彻底,且污泥在600 ℃之后主要以缩聚反应为主。通过调变热解温度及反应时间,可定向调控污泥热解产物的组成与分布。

       

      Abstract: According to the development demands of municipal sludge resource utilization and reduction disposal in China, pyrolysis technology can be used to convert municipal sludge into tar, combustible gas and char. The degree of sludge pyrolysis is adjusted by changing the reaction temperature and time. The effects of reaction degrees on the pyrolysis conversion of sludge and the distribution characteristics of pyrolysis products were investigated. The results show that different pyrolysis reaction time has a significant effect on the yield and composition of the three-phase products, and there are some differences with the change of temperature. With the extension of reaction time, the yield of char decreases gradually while the yield of gas increases greatly. At 500 ℃, compared with the reaction time of 0 min, the content of CO2 and C2-C3 increased by 171.9% and 1287.2% in 30 min respectively. However, the yield increase rate of each component in pyrolysis gas at high temperature of 700 ℃ decreased. The CO2 formed by carbonate decomposition can be gasified with sludge char to form CO. The sludge tar is mainly composed of heavy components, such as distillates with boiling point > 230°C account for more than 90%. The content of light components (< 230 ℃) in tar increased by 131.5 % (500 ℃) with the increase of reaction time, but the yield of each tar fraction changes slightly at 700 ℃. This is because when the temperature is higher (700 ℃), the thermal decomposition is carried out more thoroughly, and the sludge is mainly based on polycondensationafter 600 ℃. By adjusting the pyrolysis temperature and reaction time, the composition and distribution of sludge pyrolysis products can be directionally regulated.

       

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