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    燃煤电厂和水泥厂中的钙循环CO2捕集系统研究

    Research on calcium looping for CO2 capture systems in coal-fired power plants and cement plants

    • 摘要: 化石燃料燃烧产生的CO2是导致全球变暖的主要原因。碳捕集与封存(CCS)被认为在减少温室气体排放方面具有关键作用。目前正在进行商业规模示范的胺洗涤成熟技术是燃煤电厂改造方案的合适选择。然而,在化学吸收CO2捕集过程中,溶剂再生的能量需求导致电厂效率和功率输出大幅降低,因此需要开发具有更低效率损失的新技术。具有前景的钙循环(CaL)工艺技术因其能够减少效率损失和相关电力成本而备受关注,该技术基于钙基吸附剂在高温条件下发生的可逆碳酸化/煅烧反应,总结了将 CaL 技术整合到燃煤电厂和水泥厂中的方案,并对综合系统性能的改善方式进行了评估。针对CaL 技术整合到燃煤电厂而言,具体主要从CaL 系统中煅烧炉热量来源,如何降低煅烧炉能耗和如何获得高纯度CO2三个方面总结。针对CaL 技术整合到水泥厂而言,重点总结了设有CO2捕集系统和未设有CO2捕集系统集成于不同规模的水泥厂中所产生的CO2减排成本。表明将 CaL 技术集成于燃煤电厂后,系统效率损失为2.6%~7.9%,CO2减排成本在16~53.1 €/t,而CaL 技术集成于水泥厂后,CO2减排成本在 17.1~83.2 €/t。

       

      Abstract: CO2 generated from the combustion of fossil fuels is the primary cause of global warming. Carbon capture and storage (CCS) is considered a key approach for reducing greenhouse gas emissions. Amine scrubbing, a mature technology currently being demonstrated at a commercial scale, is a suitable retrofit option for coal-fired power plants. However, the energy demand for solvent regeneration in chemical absorption-based CO2 capture significantly reduces power plant efficiency and power output. Therefore, new technologies with lower efficiency losses need to be developed. The promising Calcium Looping (CaL) technology has garnered significant attention for its potential to reduce efficiency losses and associated electricity costs. This technology is based on the reversible carbonation/calcination reaction of calcium-based sorbents under high-temperature conditions. This review summarizes the integration of CaL technology into coal-fired power plants and cement plants, evaluating ways to improve the performance of integrated systems. For the integration of CaL technology into coal-fired power plants, the review primarily focuses on three aspects: the heat source for the calciner in the CaL system, methods to reduce calciner energy consumption, and strategies for obtaining high-purity CO2. For the integration of CaL technology into cement plants, the emphasis is on summarizing the CO2 avoided costs in cement plants of varying scales, with and without CO2 capture systems. The findings indicate that when CaL technology is integrated into coal-fired power plants, the system efficiency penalty ranges from 2.6% to 7.9%, with CO2 avoided costs between €16~€53.1/t. For integration into cement plants, the CO2 avoided costs range from €17.1~€83.2/t.

       

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