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    浮选调浆过程捕收剂在煤泥表面脱附行为研究

    Investigation of collector desorption behavior on surface of coal slurry during flotation conditioning

    • 摘要: 浮选调浆过程中进行机械搅拌是增强调浆效果常见且高效的方法,而过高的搅拌强度会造成捕收剂从煤泥颗粒表面脱附,恶化调浆效果,适宜的搅拌强度范围是增强调浆性能亟需解决的难题之一。为了探究搅拌转速对煤油吸附率的影响,同时探究煤油在煤泥表面的脱附行为,试验采用紫外分光光度计对吸附率进行测量计算,通过自行搭建的脱附试验装置和高速运动采集系统对搅拌环境下吸附油滴接触角、吸附面积、形变程度以及力的作用进行研究。研究结果表明:搅拌转速对煤泥吸附率增加有显著影响,随着搅拌转速的增加,吸附率的变化分为增加、减少和稳定3个阶段,在转速800 r/min时吸附率有最大值78.37%,过高和过低的转速都不利于调浆。随着搅拌转速的增大,吸附油滴接触角和接触面积增大,吸附效果随之增大。油滴形变程度随着转速的增加而增加,稳定性降低。

       

      Abstract: Mechanical stirring during the flotation conditioning process is a commonly employed and efficient method to enhance the effectiveness of slurry conditioning. However, excessive stirring intensity can lead to the desorption of collectors from the surfaces of coal slurry particles, thereby compromising the conditioning efficacy. Determining the optimal range of stirring intensity to enhance conditioning performance is a pressing challenge. In order to explore the influence of stirring speed on the adsorption rate of coal oil and investigate the desorption behavior of coal oil on the surface of coal slurry, experiments were conducted. Adsorption rates were measured and calculated using a UV spectrophotometer. A self-constructed desorption test apparatus and a high-speed motion capture system were employed to study the contact angle, adsorption area, deformation degree, and the forces acting on adsorbed oil droplets under stirring conditions. The research findings indicate that stirring speed significantly impacts the adsorption rate of coal slurry. With increasing stirring speed, the adsorption rate exhibits three distinct phases: increase, decrease, and stabilization. The maximum adsorption rate of 78.37% is observed at a speed of 800 r/min, highlighting the crucial role of optimal stirring speed in conditioning. Both excessively high and low speeds are detrimental to the conditioning process. As stirring speed increases, the contact angle and contact area of adsorbed oil droplets also increase, leading to an enhanced adsorption effect. Furthermore, the deformation degree of oil droplets increases with rising speed, accompanied by a reduction in stability.

       

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