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    碱性固废CO2矿化利用技术工程应用进展

    Progress in engineering application of CO2 mineralization and utilization technology for alkaline solid wastes

    • 摘要: 随着全球碳排放问题日益严重,CO2矿化技术成为应对气候变化的有效手段之一。首先提出了碳排放和气候变化的背景,指出CO2矿化技术在工业体系碳排放问题中的重要性。随后,介绍了CO2矿化技术的基本原理,包括控制CO2吸收速率的3个主要步骤和分子扩散的4种主要阻力。接着,针对矿化技术路线,从直接法和间接法方面分别介绍技术路线目前发展现状,优缺点及技术瓶颈,直接法的优点是工艺路线简单,不需加入添加剂,缺点是矿化产品中碳酸盐和杂质分离困难,造成产品利用困难,技术瓶颈在于研发高效矿化反应器及打通产品规模化应用路线,间接法的优点是可生产纯碳酸钙产品,产品价值较高,缺点是工艺复杂,消耗浸出剂,需增加额外废水、尾气处理工序,技术瓶颈在于实现浸出剂的高效循环利用,降低浸出剂消耗,并实现无害化废水废气处理。然后介绍了技术路线对应的工程示范项目,如CO2矿化养护混凝土制砖、粉煤灰矿化、电石渣矿化等,介绍了这些项目的工艺路线等基本情况,概述了项目产能、投资和目前推进情况,并对每种技术方案进行优缺点,规模化应用前景及存在问题进行论述。最后,提出了技术路线选择的适应性分析,强调了技术成熟度、应用场景匹配度、矿化产品经济性和工艺的能耗与环保性四方面的重要因素,展望了该技术推广应用的前景与挑战。对碱性固废CO2矿化技术的工程应用进展进行了详尽的概述,为碱性固废CO2矿化技术大规模应用推广提供借鉴。

       

      Abstract: As global carbon emissions become increasingly severe, CO2 mineralization technology has become one of the effective means to address climate change. Firstly, the background of carbon emissions and climate change was presented, highlighting the importance of CO2 mineralization technology in addressing carbon emissions in industrial systems. Subsequently, the basic principles of CO2 mineralization technology were introduced, including the three main steps to control the CO2 absorption rate and the four main resistances of molecular diffusion. Next, regarding the mineralization technology route, the current development status, advantages and disadvantages, and technical bottlenecks of the technology route are introduced from the perspectives of direct method and indirect method. The advantage of direct method is that the process route is simple and does not require additives. The disadvantage is that it is difficult to separate carbonates and impurities in mineralized products, resulting in difficulties in product utilization. The technical bottleneck lies in the development of efficient mineralization reactors and the integration of product scale application routes. The advantage of indirect method is that it can produce pure calcium carbonate products with high product value. The disadvantage is that the process is complex and consumes leaching agents, requiring additional wastewater and exhaust gas treatment processes. The technical bottleneck is to achieve efficient recycling of leaching agents, reduce leaching agent consumption, and achieve harmless wastewater and exhaust gas treatment. Then, the engineering demonstration projects corresponding to the technical route were introduced, such as CO2 mineralization curing concrete brick making, fly ash mineralization, carbide slag mineralization, etc. The basic information of the process routes of these projects was introduced, and the project production capacity, investment, and current progress were summarized. The advantages and disadvantages of each technical scheme, the prospects of large-scale application, and the existing problems were discussed. Finally, adaptability analysis of the technology route selection was proposed, emphasizing four important factors: technological maturity, application scenario matching, mineralization product economy, and energy consumption and environmental protection of the process. The prospects and challenges for the promotion and application of this technology were discussed. A detailed overview of the engineering application progress of alkaline solid waste CO2 mineralization technology was provided, providing reference for the large-scale application and promotion of alkaline solid waste CO2 mineralization technology.

       

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