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    煤与垃圾衍生燃料(RDF)及稻壳共烧的颗粒物生成行为

    Particulate matter formation characteristics during co-combustion between coal, Refuse-Derived Fuels (RDF) and rice husk

    • 摘要: 在实验室规模的高温沉降炉中进行六安煤(LA)、垃圾衍生燃料(RDF)以及稻壳(DK)的单烧和共烧试验,探究共烧过程中不同RDF和稻壳掺混比例对PM1、PM1-10 (Particulate Matters, PMs) 生成行为的影响。试验结果表明,单独燃烧RDF时PM1排放量最多(4.85 mg/g),单独燃烧稻壳时PM10排放量最多(23.37 mg/g)。共烧过程中,添加5% RDF+7.5% DK及5% RDF+20% DK时的PM1、PM1-10排放量均明显低于计算值,且后者减少程度最高,PM1、PM1-10的减少量分别为62.75%、66.96%,说明共烧过程中颗粒物间存在着交互作用,且该交互作用的强弱与掺混比相关。通过热力学平衡计算以及飞灰粒子的XRF、XRD、SEM-EDS分析,得出共烧过程中液相物质生成量较煤单独燃烧时增多5%~47%,大量液相物质的产生促进了黏性粒子的生成,其中富有黏性的Ca/K-Si-Al具备捕获细小颗粒和碱金属及碱土金属蒸汽的能力,可以有效促进飞灰细颗粒向粗模态转化。

       

      Abstract: In this study, single combustion and co-combustion of Lu’an coal, refuse derived fuel and rice husk were carried out in a laboratory-scaled drop tube furnace, respectively. The effects of different RDF and rice husk addition ratios on the emission of PM1 and PM1-10 were studied. The experimental results indicate that the PM1 emissions were the highest when RDF combusted alone (4.85 mg/g), while the PM10 emissions from the single combustion of husk were the highest (23.37 mg/g). During co-combustion, compared with the theoretical calculation values, the PM1 and PM1-10 emissions both significantly decreased when adding 5% RDF and 7.5% DK, 5% RDF and 20% DK. What’s more, the latter had the highest reduction degree and the reduction amounts of PM1 and PM1-10 were 62.75% and 66.96%, respectively, indicating the existence of significant interaction between particles during co-combustion, and the intensity of this interaction was related to the blending ratios. Through thermodynamic equilibrium calculations, XRF, XRD and SEM-EDS analysis of fly ash, it can be found that the amount of liquid phase substances generated during co-combustion increased by 5%-47% compared to coal combustion alone, which led to the generation of many viscous particles. The viscous Ca/K-Si-Al had the ability to capture small particles as well as alkali metals and alkali earth metals, which can effectively promote the transformation of fine particles to coarse modes.

       

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