Abstract:
Moderate or intense low-oxygen dilution (MILD) combustion is an advanced low-oxygen diluted combustion technology capable of achieving simultaneous reductions in NO
x and soot emissions. This study employs numerical simulations based on the counter-flow flame model in the chemical kinetics analysis software CHEMKIN-PRO to investigate the soot formation pathways in propane MILD combustion and their distinctions from conventional combustion. Furthermore, the effects of strain rate (50–80 s
−1) and CO₂ dilution (volume fraction: 0–60%) on soot formation pathways under MILD conditions are systematically analyzed. The results reveal that the dominant soot formation pathways in MILD combustion are: 2C
3H
3→A1, A1
−+H(+M)⇌A1(+M), A1
−+CH
4⇌A1+CH
3, A1
−+C
2H
4⇌A1+C
2H
3, C
6H
5CH
3+H=A1+CH
3 and C
4H
5−2+C
2H
2=A1+H; Compared to conventional combustion, the reaction rates of 2C₃H₃→A1 and A1
− + H(+M)⇌ A1(+M) under MILD conditions are significantly reduced, leading to suppressed A1 formation and thus inhibiting soot nucleation. Consequently, the surface mass growth rate of soot decreases by 78.6%, and the peak soot volume fraction diminishes by 83.7%. Notably, the contribution of the 2C₃H₃→A1 pathway to soot formation decreases by 7.7% under MILD combustion, while the importance of the C₆H₅CH₃+H⇌A1+CH₃ and C₄H₅
−2 + C₂H₂⇌A1+H pathways increases by 5.36% and 7.59%, respectively. Additionally, the peak soot volume fraction under MILD conditions exhibits a nonlinear dependence on strain rate, initially increasing and subsequently decreasing with rising strain rates. This behavior stems from the competitive interplay between the non-monotonic variation in nucleation rates and the continuous increase in surface growth rates. Both the physical and chemical effects of CO₂ dilution intensify with higher dilution ratios. At CO₂ dilution levels of 0−40%, the physical effect of CO₂ exerts minimal influence on peak soot volume fraction. However, CO₂ chemically promotes H consumption via the CO+OH⇌CO₂+H reaction, thereby weakening the H-abstraction-C₂H₂-addition (HACA) mechanism critical for polycyclic aromatic hydrocarbon (PAH) growth. This results in significant reductions in A1 and A4 concentrations. At 60% CO₂ dilution, the peak soot volume fraction further declines to 6.4×10
−9, demonstrating enhanced suppression of soot formation in MILD combustion.