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    重质油和低阶煤共加氢油煤浆的黏温特性

    Study on viscosity-temperature characteristics of coal-oil slurry in heavy oil and low rank coal hydro-coprocessing

    • 摘要: 针对重质油油煤浆输送过程存在沉积和阻力过大等问题,采用旋转黏度计和高温黏度仪,考察了催化裂化油浆、煤焦油重油和低阶煤共处理时的油煤浆黏温特性及变化机理。结果表明,常压低温条件下,温度对油煤浆黏度的影响很大,随温度升高,煤浆黏度起初下降较快,随后下降变缓,催化裂化油浆配制的油煤浆的活化能高于煤焦油重油配制的油煤浆。高温高压条件下,以催化裂化油浆配制的油煤浆黏度随温度升高基本呈下降趋势,在350~370 ℃黏度略有增加;以煤焦油重油配制的油煤浆的黏度随温度升高起初呈下降趋势,温度超过140 ℃时,油煤浆黏度逐渐上升,338 ℃时,黏度达到最大值,随温度进一步升高,黏度呈下降趋势。

       

      Abstract: In order to prevent settling and excessive resistance in the process of coal-oil slurry conveying,the characteristics and mechanism of viscosity of coal-oil slurry in FCC slurry,coal tar heavy oil and low rank coal co-processing were investigated by using Rotary viscosimeter and high temperature viscosity meter.The results show that temperature has a great influence on the viscosity of coal-oil slurry under normal pressure and low temperature.The viscosity of coal-oil slurry decreases rapidly at first,and then slows down with the increase of temperature.The activation energy of coal-oil slurry during FCC slurry is higher than that of coal tar heavy oil. Under the condition of high temperature and pressure,the viscosity of coal-oil slurry prepared by decreases with the increase of temperature,and increases slightly between 350 ℃ and 370 ℃.The viscosity of coal-oil slurry prepared by coal tar heavy oil initially decreases with the increase of temperature.When the temperature exceeds 140 ℃,the viscosity of coal-oil slurry begins to rise.Then the viscosity reaches the maximum value at the temperature of 338 ℃,and then decreases with the temperature further increases.

       

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