The co-pyrolysis ofBHTK and CYFL was studied in fixed bed and fluidized bed. The effects of heating rate and mixing ratioon co-pyrolysis were investigated in fixed-bed experiment. The results shows that with the increase of heating rate, the weight loss rate in⁃creased, showing a simple addition trend of single pyrolysis, and the synergistic effect of co-pyrolysis is not obvious. The effects of tem⁃perature and mixing ratio on the product distribution and the synergistic effect of co-pyrolysis oil were investigated in the fluidized bed ex⁃periment.The results shows significant synergy that when the reaction pressure is 0.1 MPa, conveying gas 15 L/ min, flow gas 25 L/ min,feed rate 1.5 kg/ h and N2 atmosphere, the mixing ratio is 30%( BHTK weight ratio), the oil yield is 18.75% at 600 ℃ , and synergisticeffect has the maximum 39.30%.Compared with coal tar, the content of S decreased from 0.6% to 0.38%, the content of C decreased from82.00% to 72.28%, and the H/ C increases from 0.095 to 0.099. The quality of oil improves significantly, phenolic compounds are main⁃ly concentrated in 3-cresol (21.80%), phenol (16.43%), 2,4-dimethylphenol (13.15%), catechol (12.53%), and naphthalene com⁃pounds are mainly concentrated in 1 - methylnaphthalene ( 45. 69%), alkylnaphthalene ( 19. 43%), and 2, 6 - dimethylnaphthalene(10.75%) and other kinds of compounds for extraction using.
China Coal Science and Industry Group Co., Ltd
Coal Science Research Institute Co., Ltd
Coal Industry Clean Coal Engineering
Technology Research Center
XIE Qiang
YU Chang
SHI Yixiang
ZHAO Yongchun
DUAN Linbo
CAO Jingpei
ZENG Jie
Monthly
1006-6772
11-3676/TD