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    (自由来稿)煤气化直接熔融还原炼铁工艺的热力学平衡分析

    Thermodynamic equilibrium analysis of coal gasification- direct smelting ironmaking process

    • 摘要: 钢铁行业作为国民经济的重要基础产业,是碳排放和能源消耗密集型产业,是节能降碳的主战场之一,基于吉布斯最小自由能原理构建了煤气化直接熔融还原炼铁工艺的热平衡模型并进行了热力学平衡分析,将煤气化直接熔融还原炼铁工艺过程分解为预还原段以及熔池段分别进行研究,探讨关键工艺参数对平衡温度、铁矿粉还原度、煤气组成以及煤气利用率的影响,在预还原段,以1300℃为限定条件划定可行的操作范围以保证产生的固相产物能够以熔融态落入熔池,粉煤进料1000 kg/h,矿煤比1.43,氧煤比0.8,水蒸气煤比0.01为预还原段的最佳操作条件,对于熔池段,最佳的操作条件为水煤气变换过程中CO转化率为0.5,将循环比为0.54的煤气重新送回熔池,配氧量为110 kg/h,此时,铁矿粉还原度为100%,H2/CO比为2.06,熔池的平衡温度为1482℃,煤耗为1 t/t-Fe,与Corex、HIsmelt等熔融还原工艺煤耗相近,但是,该工艺在煤耗为1 t/t-Fe的情况下,可同时联产甲醇525 kg,提高了能源利用效率。

       

      Abstract: The iron and steel industry serves as a vital foundation of the national economy, yet it is also highly energy-intensive and a major source of carbon emissions, making it a key focus for energy conservation and emission reduction. Based on the principle of Gibbs free energy minimization, a heat balance model was developed for the coal gasification-direct smelting reduction ironmaking process, and a thermodynamic equilibrium analysis was carried out. The process was divided into two stages, pre-reduction and molten pool, for individual investigation, focusing on the influence of key operating parameters on equilibrium temperature, iron ore reduction degree, gas composition, and gas utilization efficiency. In the pre-reduction stage, a temperature limit of 1300°C was applied to define the feasible operating range, ensuring that solid products melt before entering the molten pool. The optimal operating conditions identified were: pulverized coal feed rate of 1000?kg/h, ore-to-coal ratio of 1.43, oxygen-to-coal ratio of 0.8, and steam-to-coal ratio of 0.01. For the molten pool stage, the best performance was achieved with a CO conversion rate of 0.5 in the water-gas shift reaction, recirculating 54% of the gas back into the molten pool, and an oxygen supply rate of 110?kg/h. Under these conditions, complete reduction of iron ore (100%) was attained, with an H2/CO ratio of 2.06, an equilibrium bath temperature of 1482°C, and a coal consumption of 1?t/t-Fe—comparable to other smelting reduction processes such as Corex and HIsmelt. Notably, while maintaining the coal consumption at 1?t/t-Fe, this process co-produces 525?kg of methanol, thereby significantly improving overall energy utilization efficiency.

       

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