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    氨/氢旋流火焰的火焰结构与污染物排放特性研究

    Experimental Study on the Flame Structure and Emission Characteristics of NH3/H2 Swirl Flames

    • 摘要: 在碳中和目标与能源转型背景下,氨因其具备零碳排放潜力和良好的储运特性而被广泛关注,但其低反应活性和高NOx排放特性等问题制约了其推广应用。本文基于双旋流燃烧器,开展了氨/氢混合燃料的旋流燃烧实验,系统研究了当量比、热功率和掺氢热值比例对火焰结构、自由基分布与污染物排放的影响。实验结果表明,在氢氨火焰中,随掺氢比例增加,火焰形态由“V”型向“M”型转变后再回到“V”型,自由基信号先增强后减弱,NOx排放亦表现出明显的掺氢依赖性;火焰高度和自由基信号强度随当量比和热功率下降而降低,NO排放随当量比增加而降低。研究揭示了氢掺混对氨燃烧稳定性和污染物生成的耦合作用规律,为氨基燃料的应用提供了实验依据与理论参考。

       

      Abstract: Under the background of the carbon neutrality goal and energy transition, ammonia has attracted extensive attention due to its potential as a zero-carbon fuel, offering advantages in storage, transportation, and industrial maturity. However, its low reactivity and high NOx emissions have restricted its application. Based on a dual-swirl burner, this study carried out a swirl combustion experiment of ammonia/hydrogen mixed fuel, investigating the effects of equivalence ratio, thermal power and hydrogen blending ratio on flame structure and pollutant emissions. The results show that as the hydrogen ratio increases, the flame morphology changes from "V" shape to "M" shape and then returns to "V" shape. The chemiluminescence intensity of radicals first strengthens and then weakens, and NOx emissions also exhibit a significant dependence on the hydrogen fraction.The flame height and chemiluminescence intensity both decrease with reductions in the equivalence ratio and thermal power. NO emissions decrease as the equivalence ratio rises. The research has revealed the effect of hydrogen blending on the combustion stability and emission characteristics of ammonia flames, providing experimental basis for the application of ammonia-based fuels.

       

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